12/10/2023 0 Comments Boop noodle shirt![]() Stand Out from the Crowd with a Forget Lab Safety I Want Super Powers Shirt Believer In Freedom The Officer Tatum T-Shirt t-shirt With this shirt, you're telling the world that you're unapologetically you, and you're proud of it. Its design reflects your passion for superheroes and your desire to stand out from the crowd. This shirt allows you to express yourself in a way that's both bold and artistic. Your personality is as unique as your fingerprint, and our "Forget Lab Safety I Want Super Powers" shirt is the perfect canvas to showcase it. Show Off Your Unique Personality with a Forget Lab Safety I Want Super Powers Shirt 2nd Grade 2023 Back to School Kindness Donut Inspirational t-shirt It's not just an outfit it's a symbol of your unique style and attitude, making you a trendsetter among your peers. Crafted with attention to detail, the shirt boasts a cutting-edge design that seamlessly combines modern aesthetics with a love for superheroes. This isn't just another piece of clothing it's a style upgrade that sets you apart from the rest. Upgrade Your Style with a Forget Lab Safety I Want Super Powers Shirt mat sau I Refuse To Divorce My Wife Betty Boop t-shirtĮlevate your fashion game with our "Forget Lab Safety I Want Super Powers" shirt. ![]() With a bold and captivating design, this shirt exudes a sense of power and possibility, urging you to tap into your hidden potential. By wearing this shirt, you're declaring your readiness to break free from the ordinary and embrace the extraordinary. This unique apparel isn't just clothing it's a statement of empowerment. ![]() Unleash Your Inner Superhero with a Forget Lab Safety I Want Super Powers Shirt Babies Are Stupid Noob's Choose Abortion Shirt t-shirtĮmbrace the extraordinary with our "Forget Lab Safety I Want Super Powers" shirt, designed to help you unleash your inner superhero.
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12/10/2023 0 Comments Vsepr shapes linear![]() Inversion of a generic organic amine molecule at nitrogenĪ lone pair can contribute to the existence of chirality in a molecule, when three other groups attached to an atom all differ. Fluorine is more electronegative than nitrogen and the polarity of the N-F bonds is opposite to that of the N-H bonds in ammonia, so that the dipole due to the lone pair opposes the N-F bond dipoles, resulting in a low molecular dipole moment. In contrast to NH 3, NF 3 has a much lower dipole moment of 0.234 D. ![]() There is also a dipole associated with the lone pair and this reinforces the contribution made by the polar covalent N-H bonds to ammonia's dipole moment. As the electronegativity of nitrogen (3.04) is greater than that of hydrogen (2.2) the result is that the N-H bonds are polar with a net negative charge on the nitrogen atom and a smaller net positive charge on the hydrogen atoms. Lone pairs can contribute to a molecule's dipole moment. This is an illustration of the VSEPR theory. The repulsive force of the oxygen atom's two lone pairs pushes the hydrogen atoms further apart, until the forces of all electrons on the hydrogen atom are in equilibrium. For example, in carbon dioxide (CO 2), the oxygen atoms are on opposite sides of the carbon atom ( linear molecular geometry), whereas in water (H 2O) the angle between the hydrogen atoms is 104.5° ( bent molecular geometry). This can be seen more clearly when looked at it in two more common molecules. For example, the creation of the hydronium (H 3O +) ion occurs when acids are dissolved in water and is due to the oxygen atom donating a lone pair to the hydrogen ion. ![]() They are also involved in the formation of a dative bond. The presence of a lone pair decreases the bond angle between the bonding pair of electrons, due to their high electric charge, which causes great repulsion between the electrons. The pairs often exhibit a negative polar character with their high charge density and are located closer to the atomic nucleus on average compared to the bonding pair of electrons. Angle changes Tetrahedral structure of water Yet another considers the electron localization function (ELF). The minima of the electrostatic potential V( r) is another proposed criterion. While electron density ρ( r) itself generally does not provide useful guidance in this regard, the Laplacian of the electron density is revealing, and one criterion for the location of the lone pair is where L( r) = –∇ 2ρ( r) is a local maximum. Various computational criteria for the presence of lone pairs have been proposed. The H–O–H bond angle is 104.5°, less than the 109° predicted for a tetrahedral angle, and this can be explained by a repulsive interaction between the lone pairs. In VSEPR theory the electron pairs on the oxygen atom in water form the vertices of a tetrahedron with the lone pairs on two of the four vertices. The halogens can carry three lone pairs, such as in hydrogen chloride. Two lone pairs can be found with atoms in the chalcogen group, such as oxygen in water. ![]() Lone pairs in ammonia (A), water (B), and hydrogen chloride (C)Ī single lone pair can be found with atoms in the nitrogen group, such as nitrogen in ammonia. Nevertheless, occupied non-bonding orbitals (or orbitals of mostly nonbonding character) are frequently identified as lone pairs. In molecular orbital theory (fully delocalized canonical orbitals or localized in some form), the concept of a lone pair is less distinct, as the correspondence between an orbital and components of a Lewis structure is often not straightforward. Examples are the transition metals where the non-bonding pairs do not influence molecular geometry and are said to be stereochemically inactive. However, not all non-bonding pairs of electrons are considered by chemists to be lone pairs. They are also referred to in the chemistry of Lewis acids and bases. Lone pair is a concept used in valence shell electron pair repulsion theory (VSEPR theory) which explains the shapes of molecules. Thus, the number of electrons in lone pairs plus the number of electrons in bonds equals the number of valence electrons around an atom. Electron pairs are therefore considered lone pairs if two electrons are paired but are not used in chemical bonding. They can be identified by using a Lewis structure. Lone pairs are found in the outermost electron shell of atoms. In chemistry, a lone pair refers to a pair of valence electrons that are not shared with another atom in a covalent bond and is sometimes called an unshared pair or non-bonding pair. Pair of valence electrons which are not shared with another atom in a covalent bond Lone pairs (shown as pairs of dots) in the Lewis structure of hydroxide 12/10/2023 0 Comments Embroidery split stitch![]() Bind this edge, then stitch the two folded sides of the remaining long lengths together to form ties. Take the remaining bias binding, find the centre and place this in the middle of the neck edge. Place the wadding between the two fabrics and tack around the edges through all thicknesses.īind the outer edge of the bib with bias binding. ![]() Cut the same shape from lightweight wadding and backing fabric. Use a needle and thread to produce any number of stitchesfrom stem stitches to chain stitches, french knots and woven wheelsand decorate fabric with any design. Place a folded towel on an ironing board, put the work upside down on top and press carefully on the wrong side. An Essential Guide to Embroidery Stitches for Beginners. When you have finished the embroidery, remove the work from the hoop. Other areas can be worked with a single strand of mid-grey or dark grey, such as the soles of the rabbit’s feet and the edges of the head and ears. To emphasise certain areas of the design, such as the outline of the eyes, the whiskers and claws, thread your needle with a single strand of black thread and, still working in split stitch, carefully outline. For some of the smaller shapes, such as the centre of the kitten’s bow, the base of the cupcake and the centres of the eyes, use satin stitch instead of split stitch (see p98). Using the same thread, fill in the shape with split stitch, ensuring the lines of stitches are close together so that the fabric within the shape is completely covered. It is a good idea to start in the centre of the design and work outwards, so for the kitten you could start with the muzzle, and for the rabbit you could start with the shirt front. Thread a crewel needle with two strands of embroidery thread and outline the shape you are going to fill with a line of split stitch. Transfer your chosen embroidery design (see p81) onto the fabric in the centre of the bib shape. Trace the bib shape onto white cotton fabric but do not cut out. Download the bib template and embroidery motifs, and print. ![]() Download the template to find the colours of thread needed. 12/10/2023 0 Comments Messenger bag for women zipper top![]() Messenger briefcase: A great option for businessmen or women on the go, this bag features a more rigid design than other messenger bags as it was mainly designed for short use during office hours.They may have a flap closure, a briefcase-style handle, or both, and usually have a strap that can be worn over the shoulder. Satchel: A more sophisticated take on the messenger bag, satchels are often made of high-quality materials and feature a structured design.It may also have additional compartments and pockets for other items, and usually has a strap that can be worn over the shoulder, quite the classic, but with a modern twist. Laptop messenger bag: This easily distinguishable bag is specifically constructed to carry a laptop, and often has a padded compartment for the device itself.It usually has a flap closure and one or two straps that can be worn over the shoulders. Backpack messenger bag: One of the most unique designs definitely, this bag combines the features of a backpack and a messenger bag, and is typically larger in size than other messenger bag styles.Courier bag: A distinct bag indeed, this bag is similar to the classic messenger bag, but is often smaller in size and has a shorter strap that is meant to be worn over one shoulder instead of being worn crossbody or in any other way.Classic messenger bag: This style is typically characterized by a rectangular shape, a flap closure, and a long strap that can be worn across the body. ![]() Some of the most common messenger bag styles include: Messenger bags come in a variety of shapes and sizes, each with its own distinct features. 12/10/2023 0 Comments 2010 ford edge brake boosterHowever, if your vacuum brake booster check valve is broken or worn out, it won’t be able to maintain vacuum pressure, and you may notice that your brakes are a bit stiffer to press down than they should be.Īs this issue progresses, air bubbles will begin to form in your brake lines. The vacuum brake booster works by using engine vacuum to amplify the force of your foot to the pedal, so you don’t have to apply as much pressure to slow down your vehicle. ![]() That’s why you should have a certified mechanic inspect your brake system and repair any issues quickly. The brake booster is an important part of your braking system, and when it fails, your vehicle will be difficult to stop. This can create air bubbles in the brake line, which reduces the braking force and increases your stopping distance. When the check valve fails, air gets trapped in the vacuum hose and the diaphragm, reducing its effectiveness. When the driver presses down on the brake pedal, the vacuum inside the booster forces the diaphragm to expand, resulting in an increase in pressure against the master cylinder piston. This occurs when the check valve is no longer regulating the vacuum pressure inside the brake booster.Ī vacuum booster has two chambers separated by a diaphragm, which draws air in one side and atmospheric pressure in the other. Normally, you shouldn’t notice a problem with your brake pedal until it becomes difficult to push down. It amplifies the pressure of your foot against the master cylinder piston, and this increased force slows the vehicle. The brake booster is a part of your car’s braking system that helps reduce the amount of force needed to stop. As a result, your brakes won’t work as well and could be difficult to press. However, if your check valve is failing, your brake booster doesn’t get the full boost of vacuum it needs. ![]() This pressure increases the force from the pedal to the master cylinder, causing your car to slow down quickly and easily. When you press the brake pedal, your vacuum-assisted power brake booster works to amplify the pressure. 12/10/2023 0 Comments Southpark phone destroyer tacitcsGood days to check the PvP Store include Thursdays, Fridays, and Sundays. Many outfits can be unlocked via random purchase at the PvP Store, so be sure to check the store frequently in order to fully expand your outfit collection. There you have it, a look at how to unlock outfits and hats in South Park: Phone Destroyer. Pope Hat: In South Park: Phone Destroyer, the Pope Hat can be unlocked as a random purchase from the PvP Store at the price of 3,500 Tickets.Alien Hat: In South Park: Phone Destroyer, the Alien Hat can be unlocked as a random purchase from the PvP Store at the price of 3,500 Tickets.Ninja Outfit: In South Park: Phone Destroyer, the Ninja Outfit can be unlocked as a random purchase from the PvP Store at the price of 2,000 Tickets.Astronaut Outfit: In South Park: Phone Destroyer, the Astronaut Outfit can be unlocked as a random purchase from the PvP Store at the price of 2,000 Tickets.Manbearpig Outfit: In South Park: Phone Destroyer, the Manbearpig Outfit could be unlocked by pre-registering to play the game prior to the game's launch.Pirate Outfit: In South Park: Phone Destroyer, the Pirate Outfit can be unlocked by reaching Level 5 during the game’s special beta event.Cowboy Outfit: In South Park: Phone Destroyer, the Cowboy Outfit can be unlocked by completing the in-game tutorial. ![]() Indian Outfit: In South Park: Phone Destroyer, the Indian Outfit is available to you at the start of the game.Below, you’ll find the full list of available outfits and hats in South Park: Phone Destroyer and information on how to unlock them. Most outfits can be acquired as PvP rewards, although there are other ways to collect outfits. ![]() With Home Base unlocked, you’ll be able to begin collecting outfits in South Park: Phone Destroyer. How to Unlock Outfits in South Park: Phone Destroyer There are a few different ways in which you can unlock outfits and hats in South Park: Phone Destroyer including random purchases at the PvP Store.īefore you can begin unlocking outfits in South Park: Phone Destroyer, you’ll need to progress far enough in the game to unlock the Home Base menu option. Outfits come in two different categories the outfit itself, and the hat that pairs with the outfit. Need a little extra help unlocking South Park swag? We’ve got you covered!īelow, you’ll find a full guide on how to unlock outfits and a full list of all available outfits in South Park: Phone Destroyer. In the game, there are a variety of collectible outfits that can be unlocked for each character. For more help in Phone Destroyer, be sure to take a look at our guide on how to get more cards.If you recently started playing South Park: Phone Destroyer, you may find yourself a bit confused on how to unlock outfits. If you can grasp these three simple things, then you’ll be well on your way to starting off strong in South Park: Phone Destroyer. ![]() That way when you do purchase cards that you want, you’ll already have the necessary materials to get them upgraded and ready to rock with your current deck.Ĭlaim your free card packs, use up that extra locker unlock, and make sure you farm for materials early on. In fact, we’d suggest ignoring any card purchases for the few several hours (at least four to five hours) and just farm for materials. This will make your cards stronger, which will allow you to stand your own for much longer, which is something you’ll definitely want to do as you try to win in Phone Destroyer. While you could build up your deck early on, it’s better to spend your currency buying more upgrade materials. As you first start off in Phone Destroyer, make sure you aren’t purchasing a ton of cards. 12/10/2023 0 Comments Chat with google my business support![]() To improve our services and address issues, Business Messages collects your usage information, crash logs, and diagnostics.We share the language of your device with the business so they can respond in your preferred language.Google collects your email address for account management, but we don't share your email address with businesses you have messaged.Messages that you compose and photos that you choose to send are sent to that business, saved with cloud storage, and synced across your devices.Your name and profile photo are shared with that business.When you message a business through Business Messages: Some of this functionality uses Google Play services. Business Messages collects certain information from you to exchange messages. To exchange messages directly with businesses, click the Chat button on Search, Maps, and third party websites. Tap Set as default. The top language in your list is used as your default language.Tap Add language and choose the language you want to add.Tap General management Language and input Language.On your Android phone or tablet, open the Settings app.Important: When you change your phone's language settings, it changes the language of all apps on your phone. Language changes may take up to 24 hours to take effect. You can change your language preferences in your device settings. We don't share your language preference with them until you send a message. When you send a message to a business, we share the language of your device with them so they can respond in your preferred language when possible. You can export and download conversations to keep for your records or use in other Google products.Keep in mind this does not delete the recipient's copy. If you delete a conversation from one device, it’s permanently removed from all linked devices.You can find your conversations on any device linked to your account.Important: Conversations are saved to your Google Account. Backup your conversations with businesses ![]() The business may continue to have the conversation on their device and respond to you. Tip: When you delete a conversation, it only deletes your copy of the conversation from your device.
12/10/2023 0 Comments Andy goldsworthy for kidsThis would work well if you want to make a sculpture using something heavier like rocks or branches. See more ideas about andy goldsworthy, land art, environmental art. His art involves the use of natural and found objects to create temporary sculptural pieces which both appear naturalistic and create stark contrasts with their. You can also make your land art outdoors and photograph it rather than glueing it to paper. Explore Jennifer Madanis board 'Andy Goldsworthy for Kids', followed by 930 people on Pinterest. Andy is an environmentalist and uses only natural materials in his sculptures including. When Andy was 13, he got a job as a labourer on a farm before he began his career in art. Andy was born on 25 th July 1956 in Cheshire. The mandala as a symbol helps me to create order out of chaos, stemming from a deep internal need to commit to the completion of each piece, I have enhanced the. The key idea behind his work is to show the life cycle of the materials and ecologies he works with, focusing on the passage of time through his on-site installations.Īfter looking at some examples of Andy Goldsworthy's work head outside and observe the shapes and patterns of nature. Feel free to download and print out our Andy Goldsworthy for kids template but don't forget you can also get creative and explore other shapes, not just a spiral! Andy Goldsworthy is a well-known sculptor and photographer and example of a land artist. A short documentary created for educational purposes to teach my classes about Andy Goldsworthy and his artistic process.Andy Goldsworthy is a British artist. I will keep you updated on how my nature art experiments go.Andy Goldsworthy is a British sculptor and photographer known for creating installation and sculptures using existing materials of nature such as rocks, leaves, branches, ice, thorns, and mud among others. He then documents how his artwork changes through photography. If it interests you give it a shot! Here is a great Pinterest board with some ideas. It can be as simple as organizing some small rocks or pine cones. I strive to create models and methods for collective creativity to connect people of all ages with each other and with the natural world and to inspire joy, spontaneity, and environmental action.” The work he does is fascinating, making Andy Goldsworthy style art available to everyone, connecting them to place while working their artistic muscles. His artist statement reads, ” My endeavors are in the tradition of social sculpture, in service to nature and to society…. In a recent Linked In discussion I ran across Zach Pine’s work. A short documentary created for educational purposes to teach my classes about Andy Goldsworthy and his artistic process. Land art is art that is made directly in the landscape, sculpting the land itself into. TateShots visited him at his studio in southwest Scotland and took a walk with him through the landscape that is at the heart of his work. While it was all temporary and meant to get kids excited about playing in nature it did get at the desired result of free play, creativity, and nature connection. One of Andy Goldsworthys famous works of art is the Red Leaf Patch, which uses leaves of different colors which have been arranged in a way that they appear to. Using materials such as wood, stone and snow, Andy Goldsworthy ’s land art explores our connection with nature. This is a wonderful opportunity for the children to work with the materials they like the. My favorite hands-on kids event in 2013 was a nature play design workshop for Westmoreland Park that I organized. His work is indeed overlapping the worlds of Art and Architecture. Children to explore how many colours they can find using natural objects. It grounds students in the changes that are happening in their world and makes them stronger stewards of their environment. He is known for his work in sculpture and pho. Allin and Muriel Goldsworthy, were strict Methodists, instilling a hard work ethic into the artist from an early age. ![]() While still a young child, he moved with his family to a suburb on the outskirts of Leeds. I think this hands-on link to art, place, and nature is so important, especially for young people. Andy Goldsworthy was born in the town of Sale in Cheshire in the north of England. ![]() It is a bit of Andy’s work still inspiring me. As I look forward to 2014, I am planning some wonderful hands on nature art work with students and other young people. 12/9/2023 0 Comments Daft punk lp vinylI think “Get Lucky” sounds better on MP3, the accented drums serve the song well. Other times though, I found the vinyl version preferable. In some instances, it actually sounds better than the vinyl, since LPs can’t handle hi-hats and other similar sounds as well as the digital medium can, and this album is full of those. But I’m going to be honest, I couldn’t hear any compression or distortion, and the album never sounds “exhausting,” like an album that is too loud often does. Yeah, the MP3 version is louder than the vinyl. Since the album does come with MP3s, I thought I would compare those files to a vinyl rip. Sure that may sound like slight praise, but do you have any idea as to how many artists fuck that up? It’s crazy. Also, the files are properly labeled and tagged. No login is required, no need to give an email, all you need to do is visit a URL, punch in your passcode and viola, you get a zip of the files as high-quality 320 kpbs MP3s. And not only should Sony/Columbia be commended for that, but they also deserve credit for how it’s done. ![]() It’s kind of a drag, but thankfully a download code is included. The very end of the side two closer “Lose Yourself To Dance” is so noisy that the album actually sounded distorted, and the opening track to side three, “Touch,” had some persistent pops that lasted for the first full minute of the track. Most of the time it’s not very noticeable, but on a few occasions the surface noise got so loud that it was distracting. The records themselves are 180g black vinyl, and while they have a nice weight to them and don’t feel flimsy, my copies had more than their share of pops and crackles. It’s probably not something that 90% of the people who buy it will notice, but for those of us who collect old records, it’s pretty cool to see. One nice touch is that the retro vibe continues onto the records themselves, with each LP featuring the classic red Columbia Records label. Although if you do that, keep in mind you’ll have a hard time seeing the awesome gatefold image, a picture of the world’s coolest keyboard. If you’re the kind of person who frames vinyl or puts it out on display, this will be a good one for that. The simple cover art fits the vinyl format well. No deluxe edition, no colored vinyl, no special box set, it’s just a regular 2LP release in a nice, standard gatefold sleeve. ![]() Name a praise for the album, it’s accurate.įor all the clamor and anticipation surrounding Random Access Memories, Daft Punk sure did take the low-key route for the vinyl. You’ve never heard anything like it, but at the same time it wears its influences on it sleeve in the best ways imaginable. It re-invents dance music by taking it back to synth-pop, disco and funk all while putting its own spin on all of it. And they’re all right: the record is a game changer. By now you’ve probably listened to the album for yourself, and probably even read dozens of other, much more in-depth reviews. ![]() I’m going to be honest with both myself and you all reading this: you don’t need to read my opinion of Random Access Memories. Daft Punk is back! And they brought disco! 12/9/2023 0 Comments Storyo download![]() Navigate each stage carefully to avoid being crushed by the rotating blocks.Įxperience Kurushi Final: Mental Blocks as originally released on the PS1, enhanced with up-rendering, rewind, quick save, and custom video filters. This sequel to I.Q.: Intelligent Qube on the original PlayStation includes brain-busting modes like 100 Attack, I.Q. Strive to be the best and make it to senior year in Ape Escape Academy.Įxperience Ape Academy originally released on the PSP (PlayStation Portable) system, enhanced with up-rendering, rewind, quick save, and custom video filters. Complete a variety of fun, colorful minigames like dancing, fighting, building bonfires, and more. Allows download Instagram Stories in HD quality. Never has monkeying around in class been so rewarding. Instagram Story Downloader is a tool to download Videos and Photos from Instagram Story. Dive into modes include the story-driven Gauntlet, challenging Trials, Training, and more.Įxperience Soulcalibur: Broken Destiny originally released on the PSP (PlayStation Portable) system, enhanced with up-rendering, rewind, quick save, and custom video filters. Wield massive blades, execute high-flying maneuvers, and apply pressure to destroy rivals or knock them out of the ring. While reading the Kids StoryO and its various stories, kids of all age groups will find themselves immersed into the StoryO world. Practice and patience make perfect as you hone your combos and seek to win the tournament.Įxperience Tekken 6 as originally released on the PSP (PlayStation Portable) system, enhanced with up-rendering, rewind, quick save, and custom video filters. Customize your favorite character, equipping items with direct impacts on gameplay. PlayStation Premium | Classicsįace off against tough opponents in large, interactive stages. *All PlayStation 5 game versions are download only. *A-Train Express is available in North America only. Playstation VR users can immerse themselves in an exclusive series-first model railroad mode. This latest incarnation builds upon the features of previous entries in the series, including Shinkansen bullet trains from across Japan. Eventually, this increases reading skills and make the child to understand the world of reading better.The three elements of city development, railroad operations, and company management come together in the supreme urban planning experience. This creates great bond between you and your children. It brings not only the quiet time before bed but also gives enjoyable time for you and your children. Our online free children’s bedtime story books are enjoyable that make children to get associated with reading story with emotional warmth and joy.īedtime stories are the key to maximize joy at night. When it comes to bring up children, it is important to cultivate good habit like reading, which is a best practice to infer reading cognitive benefits in future. This brings more fun to your children’s bedtime, by reading new stories every time by downloading our free children bedtime story books online. Personalised children story books makes your children reading more skittish and enjoyable that connects them deeply by visualizing themselves in the stories.Ĭreative illustrations of stories help you dramatize the story as you read, the story are narrated in such a way, you can understand each character deeply and enact them to add more fun to child’s bedtime stories. Download popular programs, drivers and latest updates easily StoryO is an exciting tool that takes story organization to a whole other level Enter ideas onto electronic index cards, rearrange and attach them to multiple timelines and sequences, develop characters, plot points and multiple story lines. ![]() Check our free children’s bedtime story books online download to encourage your children’s reading and language development that help them to improve their literacy skills in a joyous way. Bedtime stories are great to travel into new worlds of joy, reading bedtime stories before they fall asleep can feed their brain something to digest. Download Facebook stories online using Facebook story saver. Read 2 user reviews and compare with similar apps on MacUpdate. Reading take your children to a whole new world of fiction, this in turn induce your children’s creative portion. Facebook story downloader saves your videos on your computer or mobile to watch them later. Download the latest version of StoryO for Mac for free. Make children’s bed time more fun and joyful This develops reading and storytelling skills of children, and an excellent opportunity to cultivate the young mind with our free children’s bedtime story books online. Children love bedtime stories, reading stories to them make their bedtime more joyful and fun-filled. |
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